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Wednesday, December 28, 2016

This Is What happens Inside a Battery Right Before It Explodes

Overworking or overcharging a lithium-ion battery can cause deformation in its spiral-shaped electrode. Which causes it to explode if care is not taking.

From the fiery Note 7 debacles to exploding hover-boards, lithium-ion batteries aren't doing so hot lately. A new study helps to explain how these popular power sources can turn into safety hazards.

In the paper, published in the Journal of the Electrochemical Society, scientists at the Canadian Light Source (CLS) synchrotron looked inside an overworked battery. In this case, they drained a battery until its voltage was below a critical level.

Toby Bond, Canadian Light Source

Overcharging or overworking deforms the insides of a battery. (A) shows the inside of a battery before it was misused. (B) shows how misuse causes the original design defects to become even more warped. (C) highlights the areas where warping got worse.

When we overheat or overcharge lithium ion batteries, the materials inside start to break down and produce bubbles of oxygen, carbon dioxide, and other gases. Pressure builds up, and the hot battery swells from a rectangle into a pillow shape. Sometimes the phone involved will operate afterwards. Other times it will die

To see what's happening inside the battery when it swells, the CLS team used an x-ray technique called computed tomography.

Inside the battery is an electrode that spirals out from a central point like a jellyroll. The x-ray scan revealed that the bubbles produced during overheating warped and dented this electrode.

Intriguingly, the study authors found that the worst deformation from the gas buildup occurred in areas that had slight defects before the battery was ever over-drained. The authors note that doing more studies like this, on a larger variety of batteries, would improve understanding of how these batteries respond to gas evolution, which could lead to better designs.

As New Scientist notes, it's not clear whether the Samsung Note 7 catastrophes included pillowing or this type of deformation.

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